Theoretical study of the H 3 + ion dissociative recombination process

نویسندگان

  • Chris H Greene
  • Viatcheslav Kokoouline
چکیده

We report recent developments in the theory of dissociative recombination of the H3 ion. The theory is able to explain the surprisingly large dissociative recombination rate observed in storage-ring experiments. We have found that the high rate is caused by Jahn-Teller coupling between the electronic and vibrational degrees of freedom. We compare two theoretical models: A simplified model and an improved one. The two models each produce a theoretical rate that is consistent with the storage-ring observations. The final theoretical dissociative recombination rate presented here accounts for several experimental details that are often not considered.

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تاریخ انتشار 2004